The phototransformation of 14C-[test material] was studied on [texture] soil [pH --, organic carbon --%] from [country name] at mg a.i./kg soil for d at --ΊC and --% moisture. The experiment was conducted in accordance with the (specify the Guideline followed), and in compliance with the GLP standards [specify the GLP standards followed]. [test material] was applied on the soil surface by spraying or other method. The treated samples were irradiated under natural sunlight (location; latitude; longitude; light intensity; sunlight hours) or by continuous irradiation using (type of lamp; wavelength/filter used). Test vessels were connected/not connected to traps for the collection of CO2 and organic volatiles. Samples were taken at 0, x1, --, and xn days for the determination of the parent compound and transformation products. The soil samples were extracted with (specify the solvent and/or method used), and the [test material] residues were analysed by [TLC/HPLC (detector)/GC-(detector)]. Identification of the transformation products was done by (e.g.: GC-MS, co-chromatography).
The mass balance was and -- % (mean ± s.d.) in the dark and irradiated samples, respectively. At test termination, --% of the applied 14C remained as the parent in the dark samples. [If there was transformation, incorporate the following information, otherwise state No transformation occurred in the dark samples]. The transformation products identified in the dark samples were and formed at a maximum of to -- % of the applied amount. At study termination, the CO2 and volatile organic compounds in the dark samples amounted to and --% of the applied amount, respectively. [Indicate if any of the transformation products in the dark were major or decreased after reaching the maximum.]
In the irradiated samples, concentration of the parent compound decreased from -- % at day 0 to --% of the applied amount at test termination. [If there was transformation, incorporate the following information, otherwise state No transformation occurred in the irradiated samples]. The major transformation product(s) was/were [code name(s) and chemical nomenclature], with maximum concentrations of and -- % of the applied amount, observed on the th and th day of incubation, respectively. At study termination, the corresponding concentrations were and -- % of the applied amount, respectively. The minor transformation product(s) in the irradiated samples was/were {code name(s) and chemical nomenclature} formed at a maximum of to -- % of the applied amount. [Indicate if any of the transformation products decreased after reaching the maximum.] In irradiated samples, at the end of the study, the evolved CO2 and volatile organic compounds amounted to and -- % of the applied amount, respectively. (Indicate if the volatiles were not formed). [Compare the transformation products formed in the dark and irradiated samples, and, identify and quantify the products that are formed by phototransformation only.]
Extractable [14C] residues decreased from and -- % of the applied amount at day 0, to and -- % of the applied amount at test termination, in the dark and irradiated samples, respectively. In the irradiated samples, non-extractable [14C] residues increased from -- % of the applied amount at day 0, to -- % of the applied, at the end of the study. Non-extractable residues in the dark samples was -- % of the applied amount at day 0, and -- % of the applied amount at test termination. Briefly describe the phototransformation pathway.
The half-life (lives)/DT50 (50% decline time) of [test material] in the dark and irradiated samples was/were and d, respectively. The half-life (lives)/DT50 for phototransformation was d [difference between irradiated and dark samples].
[Briefly describe the results of the supplementary experiments, if any]